Complex Salts Derived from the Reactions of Organotin(IV) with 6-Methylpyridine-2-Carboxaldehyde Phenylhydrazone: X-Ray Crystal Structure of BIS[6-Methylpyridine- 2-Carboxaldehydehydrazodium]- Tetrachlorodimethylstannate(IV)
- Resource Type
- Authors
- Brian W. Skelton; Liang-Ming Yeow; Nobuo Ishizawa; Barbara Etschmann; Guan-Yeow Yeap; Soon-Beng Teo
- Source
- Journal of Coordination Chemistry. 56:215-221
- Subject
- chemistry.chemical_classification
Schiff base
Stereochemistry
chemistry.chemical_element
Salt (chemistry)
Crystal structure
Carbon-13 NMR
Chloride
Medicinal chemistry
chemistry.chemical_compound
Monomer
chemistry
Materials Chemistry
medicine
Physical and Theoretical Chemistry
Tin
medicine.drug
Dichloromethane
- Language
- ISSN
- 1029-0389
0095-8972
Reactions of organotin(IV) chloride (Me 2 SnCl 2 , PhSnCl 3 and n -BuSnCl 3 ) with the Schiff base 6-methylpyridine-2-carboxaldehyde phenylhydrazone ( L ) result in the formation of organotin(IV) anionic complexes. Me 2 SnCl 2 reacts with L in dichloromethane to form [ L H + ] 2 [Me 2 SnCl 4 ] 2 m . X-ray structural analysis has been carried out on the complex salt bis[6-methylpyridine-2-carboxaldehydehydrazodium]tetra-chlorodimethylstannate(IV), [ L H + ] 2 [Me 2 SnCl 4 ] 2 m wherein the tin moieties exist as monomers. Reactions of PhSnC1 3 and n -BuSnCl 3 with L form the complexes [ L H + ] 2 [PhSnCl 5 ] 2 m and [ L H + ] 2 [ n- BuSnCl 5 ] 2 m . Compounds were also characterized by FTIR, 1 H and 13 C NMR spectroscopy.