Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals
- Resource Type
- Authors
- David V, Avila; K U, Ingold; J, Lusztyk; W R, Dolbier; H-Q, Pan
- Source
- The Journal of organic chemistry. 61(6)
- Subject
- Language
- ISSN
- 1520-6904
Laser flash photolysis has been used to determine the absolute rate constants for addition of several partially fluorinated n-alkyl radicals to three styrenes at 25 °C in Freon 113. Fluorination at the γ-position (RCF