Intermolecular Visible-Light Photoredox Atom-Transfer Radical [3+2]-Cyclization of 2-(Iodomethyl)cyclopropane-1,1-dicarboxylate with Alkenes and Alkynes
- Resource Type
- Authors
- Yue Qu; Yingming Yao; Pixu Li; Xiangyong Gu; Qi Yang; Xiang Li
- Source
- Chemistry - A European Journal. 19:11878-11882
- Subject
- Radical
Organic Chemistry
Intermolecular force
chemistry.chemical_element
General Chemistry
Photochemistry
Radical cyclization
Catalysis
Cyclopropane
chemistry.chemical_compound
chemistry
Cyclopentene
Lewis acids and bases
Iridium
Cyclopentane
- Language
- ISSN
- 0947-6539
Radical chemistry! A visible-light-promoted, tin/boron-free intermolecular [3+2] atom-transfer radical cyclization reaction was developed by using iridium polyphenylpridinyl complex as the sensitizer. 2-(Iodomethyl)cyclopropane-1,1-dicarboxylate reacted with various alkenes and alkynes to form cyclopentane and cyclopentene derivatives.