NiCl2 as a Cheap and Efficient Precatalyst for the Coupling of Aryl Fluorosulfonate and Phosphite/Phosphine Oxide
- Resource Type
- Authors
- Haoyuan Li; Hongbo Zhou; Hu Cai; Ying Yu; Wenjie Yan; Shengmei Guo; Huimin Hu
- Source
- Synlett. 32:1453-1456
- Subject
- Phosphine oxide
chemistry.chemical_compound
Nickel
Fluorosulfonate
chemistry
Aryl
Organic Chemistry
chemistry.chemical_element
Phenol
Phenols
Combinatorial chemistry
Phosphine
Catalysis
- Language
- ISSN
- 1437-2096
0936-5214
Herein, NiCl2 is employed as a cheap precatalyst in the formation of C(sp2)–P bond via cross-coupling reaction of phenol derivatives and phosphine oxides/phosphites. This catalytic system allows a variety of phenols with diverse functional groups to transform into phosphates with good yields. No additional additive is used in this reaction.