A large number of volatile organic compounds (VOCs) are emitted from the high temperature treatment process in the dismantling and recycling procedure of e-wastes, which has a significant impact on the surrounding environment and human health. In this study, an e-waste dismantling and recycling yard was selected to measure the VOCs concentrations and compositions in the exhaust of treatment facilities of heating baking board, plastic granulation, wet extraction, and pyrometallurgical workshops, and the emission characteristics of VOCs and emission factors for total VOCs from different production processes were investigated. The results showed that there were significant differences in total VOCs emission concentrations among different production processes. The concentrations of total VOCs produced in different workshops followed the descending order of the heating baking board (heating rotary plate furnace) process[(2096.1±732.4) μg·m