Clean hydrogen generation for utilizing in applications like chemicals manufacturing and energy production is required. The direct conversion of methane into synthesis gas (H2, CO) by various catalytic reforming processes expanding interest in recent years to produce the feed stream required for solid oxide fuel cells. So large volumes of research have been reported focusing on hydrogen generation by methane dry reforming due to the utilization of greenhouse gasses (CH4, CO2). The conversion of a renewable product provides a route to future sustainable hydrogen whilst lowering some greenhouse gases emissions. Ni0.2Sr0.8Al0.05Zr0.95O3−δ perovskite catalyst for methane reforming has been synthesised by a green, low temperature hydrothermal method based on previously published work1 . The perovskite catalyst was characterized by techniques, including powder X-ray diffraction, HR-SEM, EDS, BET, temperature programmed reduction, reaction TPR and temperature programmed oxidation TPO. The aim of this work was to develop active catalytic materials for methane reforming with high ability in suppressing coke formation using Perovskite (general formula ABO3) that been shown to be excellent catalysts.