The role of the sulfinyl group in the copper catalyzed benzyl reactions from 2-p-tolylsulfinylbenzylstannanes
- Resource Type
- Authors
- M. Belén Cid; Modesto J. Remuiñán; Sara Duce; Jesús López-Cantarero; José L. García Ruano; José Alemán
- Source
- Journal of Sulfur Chemistry. 30:370-376
- Subject
- Ortho position
chemistry
Group (periodic table)
Copper catalyzed
chemistry.chemical_element
Organic chemistry
General Chemistry
Copper
Medicinal chemistry
Palladium
Stille reaction
- Language
- ISSN
- 1741-6000
1741-5993
2-p−Tolylsulfinyl benzyltributyltin undergoes smooth coupling conditions with allyl and alkynyl derivatives in the presence of Cu(I) salts. It demonstrates that the sluggish benzyl transfer in Stille coupling reactions mediated by copper can be significantly improved by the presence of a sulfinyl group at the ortho position.