Influence of some minerals on the cellulose thermal degradation mechanisms
- Resource Type
- Authors
- M. Auber; G. Finqueneisel; Anissa Khelfa; Jean-Victor Weber
- Source
- Journal of Thermal Analysis and Calorimetry. 92:795-799
- Subject
- Thermogravimetric analysis
Reaction mechanism
Chemistry
020209 energy
Inorganic chemistry
02 engineering and technology
021001 nanoscience & nanotechnology
Condensed Matter Physics
Catalysis
Thermogravimetry
chemistry.chemical_compound
0202 electrical engineering, electronic engineering, information engineering
Degradation (geology)
Physical and Theoretical Chemistry
Cellulose
0210 nano-technology
Thermal analysis
Pyrolysis
- Language
- ISSN
- 1572-8943
1388-6150
The influence of different inorganic salts (MgCl2, ZnCl2, NiCl2 and H2PtCl6) on the primary mechanisms of cellulose thermal degradation has been conducted by using thermogravimetric (TG-DTG) and pyrolysis-mass spectrometry (Py-MS) analysis at low heating rate (10°C min-1) from ambient temperature to 500°C. The results clearly demonstrate that the used salts influence the primary degradation mechanisms. Furthermore, we can assume that some inorganic salts could be considered as specific catalysts and some others as inhibitors. MgCl2 promotes selectively initial low temperature dehydration as observed both by TG and Py-MS. ZnCl2 strongly changes the thermal behaviour of impregnated sample. The maximum mass loss rate temperature is shifted to lower temperature and on the basis of our results we can conclude that ZnCl2 acts as catalyst in all primary degradation mechanisms. NiCl2 and H2PtCl6 do not modify significantly the cellulose thermal behaviour but change the composition of both produced gases and liquids suggesting that these minerals catalyse some secondary reactions.