As its much lower thermal conductivity than other usual materials, Silica aerogel is a potentially efficient heat insulation material with the lowest bulk density. However, it is transparent for infrared light when used in high temperature. Herein, titanium oxide was added in the silica aerogel by in-situ blending. The dispersion property of titanium oxide particles, microstructure mechanical property, thermal conductivity, and thermal insulation were investigated. The results of this in-situ blending process indicated a potential application value in aerospace thermal protection industry.