In order to increase the ignition performance and combustion performance of B/PTFE fuel-rich propellant,Li-Al alloy is used to increase the sensitivity of B/PTFE fuel-rich propellant.The impact sensitivity、friction sensitivity、 combustion temperature、 burning rate combustion heat and TGA are tested.The results showed that the sensitivity、combustion heat and ignition performance increase much.The burning rate increased 30~50% and the combustion temperature was relatively stable about 800°C.