Light emitting diode (LED) is the fourth generation lighting source, but it has some shortcomings such as complex chip packaging process and the unbalanced light color of phosphor in long-time application. In this study, a kind of Eu-terephthalic acid/Tb-sulfosalicylate/ZrO2/ZnZrO3(Eu-PTA/Tb-SSA/ZrO2/ZnZrO3) phosphor with warm white light emission properties was prepared, and the warm white light LED (w-WLEDs) was successfully prepared by encapsulating Eu-PTA/Tb-SSA/ZrO2/ZnZrO3phosphors together with 270 nm UV-chip. The ZrO2/ZnZrO3, Tb-SSA/ZrO2/ZnZrO3and Eu-PTA/ZrO2/ZnZrO3samples show blue emission, green emission and red emission under deep ultraviolet (UV, 270 nm) excitation, respectively. The Tb-SSA and Eu-PTA are co-doped into ZrO2/ZnZrO3matrix with blue emission to achieve the warm white light emission, and the light color can be adjusted by controlling the doping amount of Eu3+and Tb3+. Through the excitation method of single-component phosphor by the single chip, the complex chip packaging process of w-LED can be solved. By doping rare earth organic complexes into porous ZrO2/ZnZrO3matrix, the problems of the light color unbalanced of phosphor and the low luminescence intensity of rare earth doped metal oxides composites can be solved.