Stereoselective Chlorination of New Type Baylis-Hillman Adducts by bis(Trichloromethyl)carbonate with the Aid of Catalytic Amount of Triphenylphosphine Oxide
- Resource Type
- Article
- Authors
- Zhong, Weihui; Hong, Lingjuan; Zheng, Yemin
- Source
- Letters in Organic Chemistry; April 2010, Vol. 7 Issue: 3 p229-234, 6p
- Subject
- Language
- ISSN
- 15701786; 18756255
The chlorination of the new type Baylis-Hillman adducts by bis(trichloromethyl)carbonate (BTC) with the aid of catalytic amount of triphenylphosphine oxide (Ph3PO) was achieved with high yields and high stereoselectivities. A plausible mechanism is presented.