Synthesis, Structure, and Properties of Copper(II), Nickel(II), and Cobalt(II) Ketoiminate Chelates. Molecular and Crystal Structures of Bis[2-nitro-3-(8-quinolylimino)prop-1-enoxy]cobalt(II).
- Resource Type
- Article
- Authors
- Kovaleva, T. V.; Uraev, A. I.; Lyssenko, K. A.; Vlasenko, V. G.; Burlov, A. S.; Borodkin, G. S.; Garnovskii, D. A.
- Source
- Russian Journal of Coordination Chemistry. Apr2022, Vol. 48 Issue 4, p210-217. 8p.
- Subject
- *MOLECULAR crystals
*MOLECULAR structure
*CHELATES
*CRYSTAL structure
*COBALT
*COPPER
*NICKEL
- Language
- ISSN
- 1070-3284
β-Aminovinyl ketone (2-nitro-3-(8-quinolylamino)prop-2-enal) was synthesized by condensation of nitromalondialdehyde with 8-aminoquinoline. The reactions of β-aminovinyl ketone with copper, nickel, and cobalt acetates in methanol gave metal complexes. The spectral and magnetic characteristics of preparatively isolated compounds were studied. The structure of cobalt(II) chelate was determined on the basis of X-ray diffraction study (CIF file CCDC no. 2109263). [ABSTRACT FROM AUTHOR]