Synthesis, characterization, and electrochemical properties of μ-oxalate bridged vanadium(III) and (IV) dimers incorporating the Kläui ligand, CpPORCo (R=Me,Et).
- Resource Type
- Article
- Authors
- Tarlton, Michael L.; Anderson, Alexander E.; Weberski, Michael P.; Riart-Ferrer, Xavier; Nelson, Brandon M.; McLauchlan, Craig C.
- Source
- Inorganica Chimica Acta. Aug2014, Vol. 420, p159-165. 7p.
- Subject
- *VANADIUM compounds
*COMPLEX compounds synthesis
*LIGANDS (Chemistry)
*OXALATES
*ELECTROCHEMICAL analysis
*DIMERS
- Language
- ISSN
- 0020-1693
Highlights: [•] Oxalate bridged vanadium(IV) dimers were synthesized and characterized. [•] Electrochemical analysis of oxalate bridged vanadium(IV/IV) and (III/IV) dimers. [•] X-ray crystallographic studies of novel vanadium(IV/IV) and (III/IV) dimers. [•] NMR and EPR studies of novel vanadium(IV/IV) and (III/IV) dimers were conducted. [•] Novel vanadium(IV/IV) and (III/IV) dimers have potential as oxidation catalysts. [ABSTRACT FROM AUTHOR]