Molecular Chessboard Assemblies Sorted by Site-Specific Interactions of Out-of-Plane d-Orbitals with a Semimetal Template.
- Resource Type
- Article
- Authors
- Wäckerlin, Aneliia; Fatayer, Shadi; Nijs, Thomas; Nowakowska, Sylwia; Mousavi, S. Fatemeh; Popova, Olha; Ahsan, Aisha; Jung, Thomas A.; Wäckerlin, Christian
- Source
- Nano Letters. Mar2017, Vol. 17 Issue 3, p1956-1962. 7p.
- Subject
- *METAL phthalocyanines
*MOLECULAR self-assembly
*MOLECULAR orbitals
*SUBSTRATES (Materials science)
*CHEMICAL templates
- Language
- ISSN
- 1530-6984
We show that highly ordered two-dimensional (2D) chessboard arrays consisting of a periodic arrangement of two different molecules can be obtained by self-assembly of unsubstituted metal-phthalocyanines (metal-Pcs) on a suitable substrate serving as the template. Specifically, CuPc + MnPc and CuPc + CoPc mixtures sort into highly ordered Cu/Mn and Cu/Co chessboard arrays on the square p(10 × 10) reconstruction of bismuth on Cu(100). Such created bimolecular chessboard assemblies emerge from the site-specific interactions between the central transition-metal ions and the periodically reconstructed substrate. This work provides a conceptually new approach to induce 2D chessboard patterns in that no functionalization of the molecules is needed. [ABSTRACT FROM AUTHOR]