Iodonium based regioselective double nucleophilic alkene functionalization of a hydrofluoroolefin scaffold.
- Resource Type
- Article
- Authors
- Csenki, János T.; Novák, Zoltán
- Source
- Chemical Communications. 1/18/2024, Vol. 60 Issue 6, p726-729. 4p.
- Subject
- *ALKENES
*IODONIUM salts
*NUCLEOPHILES
*FEEDSTOCK
- Language
- ISSN
- 1359-7345
Herein, we report a modular regioselective alkene difunctionalization strategy based on the use of hydrofluoroolefin (HFO) gas as fluorous feedstock material. The transformation of the HFO gas to iodonium salt creates vicinal electrophilic sites readily available for a broad range of nucleophiles. [ABSTRACT FROM AUTHOR]