By combining Cu-CTUs as metal-catalytic sites and Bodipy linkers as photosensitizers, this CMOF can catalyze terminal alkenes and alkynes to produce primary alcohols via one-pot tandem reactions with excellent regioselectivity, good overall yields for two-step reactions, broad substrate compatibility and good reusability under mild conditions. Keywords: Anti-Markovnikov Selectivity; Covalent Metal-Organic Frameworks; Primary Alcohols; Tandem Reaction EN Anti-Markovnikov Selectivity Covalent Metal-Organic Frameworks Primary Alcohols Tandem Reaction 1 1 1 08/23/23 20230828 NES 230828 B A photosensitizing b covalent metal-organic framework (CMOF) was prepared as a tandem reaction catalyst by Guo-Hong Ning, Dan Li, and co-workers in their Research Article (e202306497). Anti-Markovnikov Selectivity, Covalent Metal-Organic Frameworks, Primary Alcohols, Tandem Reaction. [Extracted from the article]