Ligand-free Pd/Cu-catalyzed decarboxylative coupling of aryl iodides with α-oxocarboxylates.
- Resource Type
- Article
- Authors
- Ji, Yongfeng; Yang, Xiaomin; Mao, Weixi
- Source
- Applied Organometallic Chemistry. Sep2014, Vol. 28 Issue 9, p678-680. 3p.
- Subject
- *CATALYSIS research
*DECARBOXYLATION
*ARYL iodides
*KETONES
*CHEMICAL yield
- Language
- ISSN
- 0268-2605
This paper describes a palladium/copper-catalyzed decarboxylative coupling of aryl iodides with α-oxocarboxylates. The gives high chemical yields of aryl ketones and has wide functional group tolerance, making the transformation an attractive alternative to the traditional approaches for aryl ketones. Copyright © 2014 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]