Organic synthesis in water/carbon dioxide microemulsions.
- Resource Type
- Article
- Authors
- Jacobson, Gunilla B.; Lee Jr., C. Ted
- Source
- Journal of Organic Chemistry. 02/19/99, Vol. 64 Issue 4, p1201. 6p. 2 Diagrams, 3 Charts, 2 Graphs.
- Subject
- *NUCLEOPHILIC reactions
*ORGANIC chemistry
- Language
- ISSN
- 0022-3263
Demonstrates the feasibility of nucleophilic reaction between hydrophilic nucleophiles and carbon dioxide soluble reactants in a water/carbon dioxide microemulsion with an anionic perfluoropolyether ammonium carboxylate surfactant. Reactions between hydrophilic nucleophiles and hydrophobic substrates; Fractionation of products via the use of supercritical fluid.