1,6‐trans‐Substituted bis(arylsulfone) trienes undergo electrocyclization followed by elimination of phenylsulfinic acid, both in the gas phase, to give (4‐phenylsulfonyl)biphenyls during sublimation. Pure, high‐quality single crystals of the product grow in the desublimation area. More information can be found in the Research Article by A. Erxleben and co‐workers (DOI: 10.1002/chem.202400672)...By Lamis Alaa Eldin Refat; Jolanta Karpinska; Saidulu Konda; John M. Simmie; Paul V. Murphy; Patrick McArdle and Andrea ErxlebenReported by Author; Author; Author; Author; Author; Author; Author [Extracted from the article]