Palladium-catalyzed desulfitative hydroarylation of alkynes with sodium sulfinates.
- Resource Type
- Article
- Authors
- Liu, Saiwen; Bai, Yang; Cao, Xiangxiang; Xiao, Fuhong; Deng, Guo-Jun
- Source
- Chemical Communications. 2013, Vol. 49 Issue 68, p7501-7503. 3p.
- Subject
- *ALKYNES
*PALLADIUM
*CATALYSIS
*HYDROCARBONS
*CLASS B metals
- Language
- ISSN
- 1359-7345
A palladium-catalyzed desulfitative hydroarylation of alkynes with aryl sulfinic acid sodium salts is described. The reaction showed good regio- and stereoselectivity, and afforded the hydroarylation products in good yields. Various functional groups were well tolerated under the optimized reaction conditions. [ABSTRACT FROM AUTHOR]