Geological maps of Earth typically incorporate field observations of rock lithology, structure, composition, and more. In contrast, conventional planetary geological maps are often made using primarily qualitative morphostratigraphic remote sensing observations of planetary surfaces. However, it is possible to define independent quantitative spectral units (SUs) of planetary surfaces, which potentially contain information about surface composition, grain size, and space weathering exposure. Here, we demonstrate a generic method to combine independently derived geomorphic and SUs, using the Rachmaninoff basin, Mercury, as an example to create a new geostratigraphic map. From this geostratigraphic map, we can infer some compositional differences within geomorphic units, which clarifies and elaborates on the geological evolution of the region. Plain Language Summary: Geological maps of rocks on Earth include information about what landforms the rocks exhibit, what they are made from, their orientation, and more. Many such details require ground observations, but these are generally not available for planetary geological maps, which rely on spacecraft data. Spacecraft images can be used to map planetary surface textures (geomorphology), but they can also be used to measure surfaces' responses to light (reflectance or emission spectra), which contain information about what the surface rocks are made from, their physical properties (e.g., grain size, roughness, porosity), and how long they have been exposed at the surface. We have combined earlier, independent geomorphic and spectral maps of the Rachmaninoff impact basin on Mercury to create a new "geostratigraphic" map that is more like a geological map that could be made of Earth. The new map highlights places that in the original geomorphic map would have been mapped all as a single unit, but are divisible based on spectral variations, attributable to differences in what the rocks are made from. This allows us to reconstruct a more detailed geological history of the region. Our method can be applied to other regions on Mercury and to other planetary surfaces. Key Points: We combine independent morphostratigraphic and spectral units of Rachmaninoff basin to create geostratigraphic unitsGeostratigraphic units can distinguish volcanic plains and impact melt in contact with each otherGeostratigraphic units imply a wider distribution of (LRM‐composition) impact melt than previously recognized [ABSTRACT FROM AUTHOR]