The inhibition of gravity segregation has been a long-standing challenge in fabrication and applications of homogeneousimmiscible alloys. Therefore, the effect of rare-earth La on the gravity segregation of Al–Bi immiscible alloys was investigatedto understand the homogenization mechanism. The results showed that the addition of La can completely suppress thegravity segregation. This is attributed to the nucleation of Bi-rich liquid phase on the in-situ produced LaBi2phase and thechange of the shape of LaBi2@Bi droplets. In addition, a novel strategy is developed to prepare the homogeneous immisciblealloys through the addition of rare-earth elements. This strategy not only is applicable to other immiscible alloys, but alsois conducive to finding more elements to suppress the gravity segregation. This study provided a useful reference for thefabrication of the homogeneous immiscible alloys.