ChemInform Abstract: Enantioselective Synthesis of 1,2-Dihydronaphthalene-1-carbaldehydes by Addition of Boronates to Isochromene Acetals Catalyzed by Tartaric Acid.
- Resource Type
- Article
- Authors
- Luan, Yi; Barbato, Keith S.; Moquist, Philip N.; Kodama, Tomohiro; Schaus, Scott E.
- Source
- ChemInform. Aug2015, Vol. 46 Issue 34, pno-no. 1p.
- Subject
- *CHEMICAL synthesis
*ACETAL resins
*CATALYSIS
*TARTARIC acid
*COUPLING reactions (Chemistry)
*ALKENYL group
- Language
- ISSN
- 0931-7597
A novel [4 + 2] cycloaddition to synthesize the title compounds bearing two chiral centers with high enantio- and diastereoselectivity is developed using the coupling reaction of isochromene acetals (I) with alkenyl boronates. [ABSTRACT FROM AUTHOR]